www.no-tillfarmer.com/articles/5829-identifying-nutrient-deficiency-symptoms-in-field-crops
Identifying Nutrient Deficiency Symptoms in Field Crops
June 12, 2016

In contrast, the relatively immobile nutrients do not readily move within the plant. As such, their deficiency symptoms first appear in new growth or young leaves and can be localized. Some of the common immobile nutrients include manganese (Mn), sulfur (S), copper (Cu), iron (Fe), calcium (Ca) and boron (B).
Macro nutrients such as N, P, K and Mg are needed in large quantities, so they are best applied to the soil. The micronutrients are needed in small qualities and can be soil and foliar applied.